About Us | MSDS/SDS Database Search | 2[]��RM�h��”�ƒ-@���,���n��b�K��%R-AI�¤~-����V8/ ZYu���X:�8ɓ���F���jHH������x�h¡�}�#�����}M��y�����l�/t�. h�bbd``b`z$��C ��H�N ��A���� � �x�6����$�[@�N !�$� ��@���+�z$zk����b`$�����@� �U P210-P231 + P232-P280-P370 + P378-P402 + P404-P403 + P235. MDL number MFCD00000038. ;�n�����/�>���"lU�Վ�t�����1���� �,�Ô�?u���Q0����!w�Wh�T2����0��mX?�����pa��M;�c�Yz�6��F��n��Ό�������P��߼Z��� w��N�at�QH�் 38 0 obj <> endobj Tax rebate rate:13.0%. After normal hours call Chemtrec at (800) 424-9300. Consult a physician. Service | It can abstract even mildly acidic protons, thus the substrate must be protected where necessary. <> Journals | 72 0 obj <>stream %PDF-1.4 Phenylmagnesium bromide, 3M in ether Revision Date 26-Feb-2020 Skin Contact Wash off immediately with plenty of water for at least 15 minutes. 0 stream Inhalation If not breathing, give artificial respiration. Biologically Active Compounds | endstream endobj startxref Show this safety data sheet to the doctor in attendance.Move out of dangerous area. %PDF-1.4 %���� X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? Consult a physician. %���� Application Phenylmagnesium bromide (PhMgBr) solution is an organomagnesium reagent mainly used in Grignard reaction, which finds application as the key step in the synthesis of (S)-2(diphenylmethyl)pyrrol idine, a chiral solvating agent for the NMR analysis.PhMgBr can also undergo palladium-catalyzed Grignard coupling with alkyl chlorides to form the cross-coupled product in good … Articles of phenylmagnesium bromide are included as well. Call a physician immediately. Wash off with soap and plenty of water. With carbon dioxide, it reacts to give benzoic acid after an acidic workup. H314 (98.59%): Causes severe skin burns and eye damage [ Danger Skin corrosion/irritation] Information may vary between notifications depending on impurities, additives, and other factors. endobj endstream endobj 39 0 obj <. VAT:17.0%. General tariff:30.0%. �>��C��9; If inhaled If breathed in, move person into fresh air. Highly sensitive Fe₃O₄ nanobeads/graphene-based molecularly imprinted electrochemical sensor for 17β-estradiol in water. �cBσN¦!��͋ٯ�A'����3K8����~.�ٙ��ύ��v� �IG�G�� �l�v�@7�+p��D���>'�����T%���^� L)�?���{C��������iOG��_��c27���u���7��Η��L����F��YΕ| ��dGdb�k�Q����ju�����i���&kر� �ƱltB¿B��ƹ������[A�/B >> �4O��{(�����fs�q�8��n��Ϋ�U�?�D���N/���&�u��������mNG/�v����/�. In case of skin contact Take off contaminated clothing and shoes immediately. Selling Leads | Remove and wash contaminated clothing and gloves, including the inside, before re-use. Product Classification | Literature: US4187099 A1, ; US4144047 A1, ; Chemsrc provides phenylmagnesium bromide(CAS#:100-58-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Phenylmagnesium Bromide is one of numerous organomagnesium Grignard reagents manufactured by American Elements under the trade name AE Organometallics™. 4 0 obj During normal hours the Health, Safety and Environmental Department. 158, p. 209 - 240, Literature: Clin Midy Patent: US3966793 A1, 1976 ; US 3966793 A. Linear Formula C 6 H 5 MgBr . << 2 Composition/Data on components: Chemical characterization: Description: (CAS#) Phenylmagnesium bromide (CAS# 100-58-3): 40-50% Diethyl ether (CAS# 60-29-7): 50-60%. MFN tariff:6.5%. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). Articles of phenylmagnesium bromide … A novel molecularly imprinted electrochemical sensor based on Fe3O4 nanobeads immobilized on graphene (Fe3O4-MIP@RGO) has been developed for detecting 17β-estradiol (17β-E2) in water using reversible ... Get all suppliers and price by the below link: Home | /Producer(Sub Systems, Inc.)/CreationDate(D:20200226195344+05'00')/ModDate(D:20200226195344+05'00')/Creator(Sub Systems, Inc.) Organometallics are useful reagents, catalysts , and precursor materials with applications in thin film deposition , industrial chemistry , pharmaceuticals , LED manufacturing , and others. ?���t#_n|��z%�4�n����#(!���:Ȇl�M�D���?ܽ��? Molecular Weight 181.31 . Remove from exposure, lie down. Buying Leads | 3 … Shanghai Jizhi Biochemical Technology Co., Ltd, Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter, 2931900090. other organo-inorganic compounds. m�7;*`��v�MǑ�����&g�`#�g��>�v��:���g~�;A��F���&���~�F;��`�����|R��ͧ��4�0�0���K�sN\�} It often adds to carbonyls, such as ketones, aldehydes. "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k�������u��=���� ��f.�蟗��y_�j6}Yɗ���2�3 �> q�B�-��i����%�m���Si��=�J{�n?�'�{;{;�E0����k"^�8�ö����$���p�>�ٞ����]����.dR*{�;?H��қ$������}ν��D��o��^��/ȏw����;�?EW��>��5h$���l�/�⼘fmQ-��Ȕ���b�1���0�^��l=m��"�������������r�],�X/�I]-�Y>J�}��4o�y�����ۿ��O2[5N}s�ഃ����?��т���� ��zY-���$F�?x�xU;Q�����"1M�cJ�|)�k���6���}v�vP��z�0�e�K��i�Z����P��������4����;j��gT��R�����! Chemsrc provides phenylmagnesium bromide(CAS#:100-58-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Disclaimer, Copyright © 2018 ChemSrc All Rights Reserved, Literature: WO2008/156817 A2, ; Page/Page column 140-141 ; WO 2008/156817 A2, Literature: Molecular Crystals and Liquid Crystals (1969-1991), , vol. Beilstein/REAXYS Number 3588849 . If not breathing, give artificial respiration. PubChem Substance ID 24855569 %%EOF ]ڨ��S�G�+��&��C�y�X���A> ����HO�6�y��n��͂�Q��m;�w��(�U�y���ז�ͫ/w�I�,���j-���+�}�����z��n5��&Wbz:������pz��vت�t�,�W�+���G�7��m���v�?�}R��w�_;������Y�8 �*�M 60 0 obj <>/Encrypt 39 0 R/Filter/FlateDecode/ID[<6A41C42EE502D94B97BA14A3F2725CB7>]/Index[38 35]/Info 37 0 R/Length 104/Prev 59902/Root 40 0 R/Size 73/Type/XRef/W[1 2 1]>>stream Phenylmagnesium bromide solution 3.0 M in diethyl ether CAS Number 100-58-3. 1 0 obj Phenylmagnesium bromide is a strong nucleophile as well as a strong base.